Sample interview questions: How do you calculate enthalpy change in a chemical reaction?
Sample answer:
- Define the System and Reaction of Interest:
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Clearly identify the system undergoing the chemical reaction and define the reaction of interest.
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Determine the Initial and Final States:
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Specify the initial state (reactants) and the final state (products) of the reaction.
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Calculate the Enthalpy Change:
- ΔH = H(products) – H(reactants)
- H(products): Enthalpy of the products in their final state
- H(reactants): Enthalpy of the reactants in their initial state
Methods for Calculating Enthalpy Change:
- Direct Calorimetry:
- Use a calorimeter to measure the heat released or absorbed during the reaction.
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ΔH = -Q, where Q is the heat flow.
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Indirect Calorimetry:
- Use thermochemical data, such as heats of formation, to calculate ΔH.
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ΔH = ΣH(products) – ΣH(reactants)
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Hess’s Law:
- Use enthalpy data from other reactions to calculate ΔH for the reaction of interest.
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ΔH = ΣΔH(sub-reactions)
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Bond Enthalpies:
- Estimate ΔH based on the bond enthalpies of the reactants and products.
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ΔH = ΣH(bonds broken) – ΣH(bonds formed)
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Quantum Mechanical Calculations:
- Use computational meth… Read full answer