How do you calculate the critical point of a substance?

Sample interview questions: How do you calculate the critical point of a substance?

Sample answer:

The critical point of a substance represents the temperature and pressure conditions at which the liquid and gaseous phases become indistinguishable. To calculate the critical point, follow these steps:

1. Determine the Critical Temperature (Tc):

  • Use experimental data or thermodynamic equations of state to determine the boiling point of the liquid at various pressures.
  • Plot the data as a graph of pressure versus temperature.
  • Extrapolate the data to the temperature where the vapor pressure curve and the liquid-vapor equilibrium curve meet. This point represents the critical temperature (Tc).

2. Determine the Critical Pressure (Pc):

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